Corrosion of Copper and Steel Under Atmospheric Conditions

Authors

DOI:

https://doi.org/10.19136/jobs.a12n34.6674

Keywords:

atmospheric aggressiveness, pollutants, corrosion, metals, ISO Standards

Abstract

The research was carried out in a rural-urban environment with the aim of evaluating the atmospheric corrosion of carbon steel and copper. To determine the corrosivity category of the environment, the ISO 9223 standard was used. Air pollutants were determined according to the methodologies and protocols described in ISO 9225, using the wet sail method to measure chloride ions (Cl-) and the sulfation dish to detect sulfur dioxide (SO2). The results indicate that the pollutant SO2 is classified within the parameters P0 to P1, indicating low levels of corrosive potential, while the pollutant Cl- is assigned an aggressiveness index of S2, recognized as high. Regarding the category of corrosivity of the materials in the study environment, carbon steel showed a C2 classification defined as low, copper category C1 interpreted as very low.

Author Biographies

  • Osiris Angélica López Zapata, Universidad Juárez Autónoma de Tabasco

    Egresada de la Licenciatura en Ingeniería Química, Maestra en Ciencias en Ingeniería, sus líneas de investigación son gases de efecto invernadero y Evaluación de materiales a la atmósfera.

     

  • Ebelia Del Angel Meraz, Universidad Juárez Autónoma de Tabasco

    Profesora-Investigadora Universidad Juárez Autónoma de Tabasco, Líneas de Investigación; Corrosión Atmosférica, Evaluación de materiales a la atmosfera , Almacenamiento de energía.

    Miembro del sistema Nacional de Investigadores Nivel 1.

  • Francisco Eduardo Corvo Pérez, Autonomous University of Campeche

    Profesor-Investigador de la Universidad Autónoma de Campeche y del Centro de Investigación en Corrosión (CICORR) . Líneas de Investigación: Corrosión Atmosférica. Miembro del Sistema Nacional de Investigadores Nivel II

     

  • Cecilia Silvia Valdés Clemente, Centro Nacional de Investigaciones Científicas

    Ingeniera Química por el Instituto Superior Politécnico José Antonio Echeverría (ISPJAE): La Habana, Cuba, Doctora en Ciencias Técnicas por la Universidad  Tecnológica de La Habana "José Antonio Echeverría": La Habana, Cuba. Especialista en Protección de Materiales (materiales pétreos y metales) y en contaminación

References

[1] S. Mitali, J. Harsh, K. Devanshu, K. Santosh, and K. Rakesh, “Overview on corrosion, classification and control measure: a study,” i-manager’s Journal on Future Engineering and Technology, vol. 17, no. 2, p. 26, 2022, doi: 10.26634/JFET.17.2.18501.

[2] B. Daneshian, D. Höche, O. Ø. Knudsen, and A. W. B. Skilbred, “Effect of climatic parameters on marine atmospheric corrosion: correlation analysis of on-site sensors data,” Materials Degradation , vol. 7, no. 1, pp. 1–10, Feb. 2023, doi: 10.1038/s41529-023-00329-6.

[3] Fuad Khoshnaw, Ed., “Part I: General Aspects of Corrosion, Corrosion Control, and Corrosion Prevention,” in Corrosion Atlas Case Studies, Elsevier, 2024, pp. xxix–xlvi. doi: 10.1016/B978-0-443-13228-5.09993-1.

[4] ISO, “ISO 9223:2012 Corrosion of metals and alloys-Corrosivity of atmospheres-Classification, determination, and estimation,” 2012.

[5] I. O. Wallinder and C. Leygraf, “Environmental Effects of Metals Induced by Atmospheric Corrosion,” ASTM Special Technical Publication, no. 1421, pp. 185–199, 2002, doi: 10.1520/STP10893S.

[6] J. Rodriguez-Yáñez, J. Uruchurtu-Chavarin, and J. Sanabria-Chinchilla, “Tropical atmospheric corrosion of galvanized steel, in a light urban atmosphere in the San José valley of Costa Rica,” Rev Mex Ing Quim, vol. 21, no. 2, pp. 1–26, Jun. 2022, doi: 10.24275/rmiq/Mat2759.

[7] J. O. Castillo-Miranda and F. J. Rodríguez-Gómez, “Mapping of the cost of atmospheric corrosion of zinc and galvanised steel due to the effect of atmospheric pollution in the Mexico City Metropolitan area,” https://doi.org/10.1080/1478422X.2022.2074115, vol. 57, no. 5, pp. 408–419, Aug. 2022, doi: 10.1080/1478422X.2022.2074115.

[8] “Cunduacán | Portal Tabasco.” Accessed: May 11, 2024. [Online]. Available: https://tabasco.gob.mx/cunduacan

[9] B. G. Díaz, E. D. Á. Meraz, and M. A. P. Castro, “Composición Fisicoquímica del agua en Cunduacán, Tabasco México.,” Journal of Energy, Engineering Optimization and Sustainability, vol. 5, no. 2, pp. 127–146, Dec. 2021, doi: 10.19136/JEEOS.A5N2.4993.

[10] M. Nogal, E. Bastidas-Arteaga, and H. M. Dos Santos Gervásio, “Consideration of climate change-induced corrosion by structural codes,” IABSE Congress, Christchurch 2020: Resilient Technologies for Sustainable Infrastructure - Proceedings, pp. 1064–1070, 2020, doi: 10.2749/CHRISTCHURCH.2021.1064.

[11] D. González Terrazas, A. Vermonden Thibodeau, and F. Gress Carrasco, “Municipios Vulnerables al Cambio Climático con base en los resultados del Atlas Nacional de Vulnerabilidad al cambio climático,” 2021. [Online]. Available: https://www.gob.mx/inecc

[12] ISO 8565, “ISO 8565:2011 Metals and alloys Atmospheric corrosion testing General requirements,” 8665, 2011.

[13] ISO 9225, “ISO 9225:2012(E) Corrosion of metals and alloys-Corrosivity of atmospheres-Measurement of environmental parameters affecting corrosivity of atmospheres,” 2012.

[14] “Servicio Meteorológico Nacional.” Accessed: Nov. 08, 2023. [Online]. Available: https://smn.conagua.gob.mx/es/

[15] M. Hoseinpoor, T. Prošek, L. Babusiaux, and J. Mallégol, “Toward more realistic time of wetness measurement by means of surface relative humidity,” Corros Sci, vol. 177, p. 108999, Dec. 2020, doi: 10.1016/J.CORSCI.2020.108999.

[16] M. E. Del Angel, L. Veleva, and A. Acosta, “Agresividad atmosférica basada en el tiempo de humectación del clima tropical húmedo del estado de Tabasco,” Universidad y ciencia, vol. 25, no. 2, pp. 111–120, 2009, Accessed: Sep. 22, 2024. [Online]. Available: http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0186-29792009000200001&lng=es&nrm=iso&tlng=es

[17] A. S. Domínguez, E. D. A. Meraz, and A. E. C. Pérez, “La Corrosión del Acero Galvanizado en una Atmósfera marina-costera de Tabasco, México.,” Journal of Energy, Engineering Optimization and Sustainability, vol. 5, no. 2, pp. 147–162, Dec. 2021, doi: 10.19136/JEEOS.A5N2.4710.

[18] M. Almazroui, K. S. Balkhair, M. N. Islam, and Z. Şen, “Climate Change Impact on Monthly Precipitation Wet and Dry Spells in Arid Regions: Case Study over Wadi Al-Lith Basin,” Advances in Meteorology, vol. 2017, no. 1, p. 5132895, Jan. 2017, doi: 10.1155/2017/5132895.

[19] B. F. Zaitchik, M. Rodell, M. Biasutti, and S. I. Seneviratne, “Wetting and drying trends under climate change,” Nature Water 2023 1:6, vol. 1, no. 6, pp. 502–513, May 2023, doi: 10.1038/s44221-023-00073-w.

[20] W. Thandar, Y. Y. K. Win, T. Khaing, Y. Suzuki, K. Sugiura, and I. Nishizaki, “Investigation of Initial Atmospheric Corrosion of Carbon and Weathering Steels Exposed to Urban Atmospheres in Myanmar,” International Journal of Corrosion, vol. 2022, 2022, doi: 10.1155/2022/4301767.

[21] C. Titakis and P. Vassiliou, “Evaluation of 4-Year Atmospheric Corrosion of Carbon Steel, Aluminum, Copper and Zinc in a Coastal Military Airport in Greece,” Corrosion and Materials Degradation 2020, Vol. 1, Pages 159-186, vol. 1, no. 1, pp. 159–186, May 2020, doi: 10.3390/CMD1010008.

[22] A. C. Santa, D. A. Montoya, J. A. Tamayo, M. A. Gómez, J. G. Castaño, and L. M. Baena, “Atmospheric corrosion of carbon steel: Results of one-year exposure in an andean tropical atmosphere in Colombia,” Heliyon, vol. 10, no. 8, p. e29391, Apr. 2024, doi: 10.1016/J.HELIYON.2024.E29391.

[23] R. Vera et al., “Atmospheric corrosion and impact toughness of steels: Case study in steels with and without galvanizing, exposed for 3 years in Rapa Nui Island,” Heliyon, vol. 9, no. 7, p. e17811, Jul. 2023, doi: 10.1016/J.HELIYON.2023.E17811.

[24] C. Titakis and P. Vassiliou, “Evaluation of 4-Year Atmospheric Corrosion of Carbon Steel, Aluminum, Copper and Zinc in a Coastal Military Airport in Greece,” Corrosion and Materials Degradation 2020, Vol. 1, Pages 159-186, vol. 1, no. 1, pp. 159–186, May 2020, doi: 10.3390/CMD1010008.

[25] P. Melo, M. Echagüe, C. Guerra, Q. Jin, M. Sancy, and A. Paul, “On the effect of simulated contamination of chlorides and sulfates on steel rebar corrosion: Electrochemical behavior and surface analysis,” Constr Build Mater, vol. 359, p. 129337, Dec. 2022, doi: 10.1016/j.conbuildmat.2022.129337.

[26] P. Zhang, X. Yue, Y. Sun, H. Zhou, J. Zhang, and Y. Wang, “Research on the mechanism of microbial corrosion in the subsurface layer of 7075 aluminum alloy under different corrosion environments with ultra low temperature double increase effect,” Vacuum, vol. 227, p. 113348, Sep. 2024, doi: 10.1016/J.VACUUM.2024.113348.

[27] D. de la Fuente, J. Simancas, and M. Morcillo, “Morphological study of 16-year patinas formed on copper in a wide range of atmospheric exposures,” Corros Sci, vol. 50, no. 1, pp. 268–285, Jan. 2008, doi: 10.1016/J.CORSCI.2007.05.030.

[28] X. Wang et al., “Atmospheric corrosion of T2 copper and H62 brass exposed in an urban environment,” Mater Chem Phys, vol. 299, p. 127487, Apr. 2023, doi: 10.1016/J.MATCHEMPHYS.2023.127487.

[29] O. O. Ekerenam et al., “Advancements in corrosion studies and protective measures for copper and copper-based alloys in varied environmental conditions,” Results in Engineering, p. 105257, May 2025, doi: 10.1016/J.RINENG.2025.105257.

[30] O. O. Ekerenam et al., “Advancements in corrosion studies and protective measures for copper and copper-based alloys in varied environmental conditions,” Results in Engineering, p. 105257, May 2025, doi: 10.1016/J.RINENG.2025.105257.

[31] I. Hamidah et al., “Corrosion of copper alloys in KOH, NaOH, NaCl, and HCl electrolyte solutions and its impact to the mechanical properties,” Alexandria Engineering Journal, vol. 60, no. 2, pp. 2235–2243, Apr. 2021, doi: 10.1016/J.AEJ.2020.12.027.

[32] T. J. Mathew et al., “Advances in distillation: Significant reductions in energy consumption and carbon dioxide emissions for crude oil separation,” Joule, vol. 6, no. 11, pp. 2500–2512, Nov. 2022, doi: 10.1016/J.JOULE.2022.10.004.

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Published

2026-08-31

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Section

Artículo científico

How to Cite

López Zapata, O. A., Del Angel Meraz, E., Corvo Pérez, F. E., & Valdés Clemente, C. S. (2026). Corrosion of Copper and Steel Under Atmospheric Conditions. JOURNAL OF BASIC SCIENCES, 12(34), 01-14. https://doi.org/10.19136/jobs.a12n34.6674